Educational toddler and preschooler playlists on you tube:
For the Toddler http://www.youtube.com/playlist?list=PL0BB1027743F0F184&feature=plcp
More for the Toddler http://www.youtube.com/playlist?list=PL47CC3766A5C63027&feature=plcp
Muffin Songs nursery rhymes http://www.youtube.com/watch?v=nUeS6gabSkE&feature=results_main&playnext=1&list=PL9FDA79DC8AB4A032
Pocoyo http://www.youtube.com/watch?v=1snLGSk0cco&list=PL070BAED0346B99C5&feature=plcp
Let's Go Pocoyo http://www.youtube.com/watch?v=J-RFJj6XMuI&list=PL7BFEF6EF8ADA71A6&feature=plcp
Sesame Street http://www.youtube.com/watch?v=OtRFHHuDdnE&list=PL672B211BD01B39EB&feature=mh_lolz
Gamequarium educational videos http://www.gamequarium.org/dir/SqoolTube_Videos/Early_Childhood/